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| Title | : | Kinetic electrode reactions in silver electrodeposition using a multipulse current measurement |
| Authors | : | Saitou, Masatoshi |
| Authors alternative | : | 斉藤, 正敏 |
| Issue Date | : | 2005 |
| Abstract | : | The kinetics of electrode reactions in silver electrodeposition are investigated using a multipulse current measurement. The transient voltage drops across the anode and cathode electrodes in response to the applied multipulse currents are measured and analyzed with an analytical solution of unsteady-state equations comprising diffusion of ions, charge-transfer reactions, and a charging process of the electrochemical double layer. The measured voltage-time curves agree well with those predicted by the analytical solution. The kinetic constant, the exchange current density, and the double-layer capacitance, which characterize the kinetics of the electrode reactions, are determined. |
| Type Local | : | 雑誌掲載論文 |
| ISSN | : | 00134651 |
| Publisher | : | Electrochemical Society |
| URI | : | http://hdl.handle.net/20.500.12000/150 |
| Citation | : | Journal of the Electrochemical Society Vol.152 no.3 p.C113 -C115 |
| Appears in Collections | : | Peer-reviewed Journal Articles (Faculty of Engineering)
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Files in This Item:
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| JES_152(3)C113.pdf | | 74Kb | Adobe PDF | View/Open |
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