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Title :Kinetic electrode reactions in silver electrodeposition using a multipulse current measurement
Authors :Saitou, Masatoshi
Authors alternative :斉藤, 正敏
Issue Date :2005
Abstract :The kinetics of electrode reactions in silver electrodeposition are investigated using a multipulse current measurement. The transient voltage drops across the anode and cathode electrodes in response to the applied multipulse currents are measured and analyzed with an analytical solution of unsteady-state equations comprising diffusion of ions, charge-transfer reactions, and a charging process of the electrochemical double layer. The measured voltage-time curves agree well with those predicted by the analytical solution. The kinetic constant, the exchange current density, and the double-layer capacitance, which characterize the kinetics of the electrode reactions, are determined.
Type Local :雑誌掲載論文
ISSN :00134651
Publisher :Electrochemical Society
URI :http://hdl.handle.net/20.500.12000/150
Citation :Journal of the Electrochemical Society Vol.152 no.3 p.C113 -C115
Appears in Collections:Peer-reviewed Journal Articles (Faculty of Engineering)

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