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No.15 (1972/03) >

 
Title :ヨウ素-オレフィン錯体について
Title alternative :Study of Iodine-Olefin Complexes
Authors :当真, 嗣徳
金城, 嘉昭
金城, 昭夫
Authors alternative :Toma, Shitoku
Kinjo, Yoshiaki
Kinjo, Akio
Issue Date :1-Mar-1972
Abstract :Charge- transfer complexes between iodine and olefins were studied spectrophotometrically in n- hexane solutions. The experiments were carried out in the room with a dim light to avoid the addition reaction. The equilibrium constants were determined to be 0.52, 1.ll, 0.44, 0.63 and 1.73 l./mol for l - hexene, I-heptene, 1 - octent, 1 - decent and cyclohexene complex at 25℃. The heat of formation and enthropy change fall in the range of - l.71 ~ -2 .28 Kcal /mol and of -6.01~ - 7.37 e. u., respectimcly.  
Type Local :紀要論文
Publisher :琉球大学理工学部
URI :http://hdl.handle.net/20.500.12000/23462
Citation :琉球大学理工学部紀要. 理学編 = Bulletin of Science & Engineering Division, University of Ryukyus. Mathematics & natural sciences no.15 p.51 -58
Appears in Collections:No.15 (1972/03)

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