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No.15 (1972/03) >

 
Title :1、3、5-トリアリル-2-ピラゾリンの光酸化反応
Title alternative :Photochemical Oxidation of 1.3.5-triaryl1-2-pyrazoline.
Authors :外間, 宏三
与儀, 誠一
Authors alternative :Hokama, Kozo
Yogi Seiichi
Issue Date :1-Mar-1972
Abstract :1,3,5-triaryl- 2-pyrazoline was irradiated with an ultraviolet light in ethanol under an oxygen atmosphere. The main products were 1.3, 5-triarylpyrazole (1.3, 5-triphenyl-2-pyrazoline to give 1.3, 5-tripheny - pyrazole in a 65% yield. 1,5-diphenyl- 3-(p-methylphenyl)-2-pyrazolioe to give1.5- diphenyl-3-(p-methylphenyl) - pyrazole in a 82% yield, 1,5-diphenyl - 3- (p-methoxyphenyl)-2 -pyrazoiine to give 1,5 – dipheny l- 3 - (p- methoxyphenyl)- pyrazole in a 65% yield and l,5- diphenyl - 3 - (p-chlorophenyl) -2-pyrazoline to give 1,5- diphenyl-3-(p- chlorophenyl )- pyrazole in a 56% yield). The reaction were followed by the determination of the disappearance of pyrazoline and that of the formation or pyrazole, Samo reactions of these compounds are described.
Type Local :紀要論文
Publisher :琉球大学理工学部
URI :http://hdl.handle.net/20.500.12000/23463
Citation :琉球大学理工学部紀要. 理学編 = Bulletin of Science & Engineering Division, University of Ryukyus. Mathematics & natural sciences no.15 p.59 -65
Appears in Collections:No.15 (1972/03)

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